Iodosobenzene diacetate, 98+%

Description

CAS: 3240-34-4 | C10H11IO4 | 322.098 g/mol

Iodosobenzene is used as an oxidizing and acetoxylating agent in organic synthesis. It is actively involved in the preparation of (Z)-3,7-dimethyl-2,6-octadien-1-al(neral) from (Z)-3,7-dimethyl-2,6-octadien-1-ol (nerol) in presence of 2,2,6,6-tetramethylpiperidin-1-oxyl (TEMPO). It is a useful reagent for the synthesis of a wide variety of heterocyclic compounds. It is also used in the Pd-catalyzed 2-arylation of indoles.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Iodosobenzene is used as an oxidizing and acetoxylating agent in organic synthesis. It is actively involved in the preparation of (Z)-3,7-dimethyl-2,6-octadien-1-al(neral) from (Z)-3,7-dimethyl-2,6-octadien-1-ol (nerol) in presence of 2,2,6,6-tetramethylpiperidin-1-oxyl (TEMPO). It is a useful reagent for the synthesis of a wide variety of heterocyclic compounds. It is also used in the Pd-catalyzed 2-arylation of indoles.

Solubility
Insoluble in water.

Notes
Light sensitive. Incompatible with strong oxidizing agents.

Specifications

Chemical Identifiers

• CAS: 3240-34-4
• Molecular Formula: C10H11IO4
• Molecular Weight (g/mol): 322.098
• MDL Number: MFCD00008692
• InChI Key: ZBIKORITPGTTGI-UHFFFAOYSA-N
• Synonym: iodobenzene diacetate, diacetoxyiodo benzene, iodosobenzene diacetate, phenyliodine diacetate, phenyliodo diacetate, phenyliodoso acetate, phenyliodosodiacetate, phenyliodoso diacetate, bis acetato phenyliodine, benzene, diacetoxyiodo
• PubChem CID: 76724
• IUPAC Name: [acetyloxy(phenyl)-$l^{3}-iodanyl] acetate
• SMILES: CC(=O)OI(C1=CC=CC=C1)OC(=O)C

• Melting Point: 159°C to 161°C
• Quantity: 25 g
• Beilstein: 1879369
• Sensitivity: Light sensitive
• Solubility Information: Insoluble in water.
• Formula Weight: 322.1
• Percent Purity: ≥98%
• Chemical Name or Material: Iodosobenzene diacetate

Safety and Handling

Hazard Category	H302+H312-H315-H319-H335
Hazard Statement	GHS H Statement H315-H319-H335 Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statement	P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c
EINECSNumber	221-808-1
RTECSNumber	DA3525000
TSCA	Yes
Recommended Storage	Ambient temperatures

SDS

RUO – Research Use Only