m-Anisidine, 98%

Catalog No.	Quantity
AAA1081530	250 g
AAA1081518	50 g
AAA108150B	1000 g

Catalog No. AAA1081530 Supplier Thermo Scientific Chemicals Supplier No. A1081530

Description

CAS: 536-90-3 | C7H9NO | 123.155 g/mol

The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.

Solubility
Soluble in water(18g/L).

Notes
Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Specifications

Chemical Identifiers

• CAS: 536-90-3
• Molecular Formula: C7H9NO
• Molecular Weight (g/mol): 123.155
• MDL Number: MFCD00007783
• InChI Key: NCBZRJODKRCREW-UHFFFAOYSA-N
• Synonym: m-anisidine, 3-aminoanisole, m-methoxyaniline, 3-methoxybenzenamine, 3-anisidine, m-aminoanisole, benzenamine, 3-methoxy, m-anisylamine, 1-amino-3-methoxybenzene, unii-jxa144kx2i
• PubChem CID: 10824
• IUPAC Name: 3-methoxyaniline
• SMILES: COC1=CC=CC(=C1)N

• Melting Point: -1°C
• Density: 1.101
• Boiling Point: 250°C to 251°C
• Flash Point: 126°C (258°F)
• Odor: Characteristic
• Refractive Index: 1.581
• Quantity: 250 g
• UN Number: UN2431
• Beilstein: 386119
• Sensitivity: Light sensitive
• Merck Index: 14,667
• Solubility Information: Soluble in water(18g/L).
• Formula Weight: 123.16
• Percent Purity: 98%
• Chemical Name or Material: m-Anisidine

Safety and Handling

Hazard Category	H302+H332-H311-H373
Hazard Statement	GHS H Statement H311-H373-H302-H332 Toxic in contact with skin. May cause damage to organs through prolonged or repeated exposure. Harmful if swallowed. Harmful if inhaled.
Precautionary Statement	P260-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P312-P314-P330-P361-P363-P501c
DOTInformation	Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: ANISIDINES
EINECSNumber	208-651-4
RTECSNumber	BZ5408000
TSCA	Yes
Recommended Storage	Ambient temperatures

SDS

RUO – Research Use Only