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Sigma Aldrich Methacryloyl chloride

Catalog No. 523216100ML Shop All MilliporeSigma Sigma Organic Chemistry Products
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52-321-6100ML 100 mL
52-321-61L 1 L
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MilliporeSigma Sigma Organics products encompass a wide range of quality reagents, solvents, catalysts, and building blocks for organic synthesis. From benchtop discovery to process development and scale-up, Sigma Organics solutions are built to meet the needs of synthetic chemists.

Methacryloyl chloride is the clear to slightly colored acid chloride of methacrylic acid. Monomethyl ether hydroquinone is added as a stabilizer to prevent auto polymerization. Reaction with diisopropyl ether in presence of metal salts is rigorous.Methacryloyl chloride is used in the manufacture of polymers:Monomer 2-methacrylamido-caprolactam was prepared by reacting methacryloyl chloride with racemic a-amino-e-caprolactam.Functional monomer was prepared by reacting methacryloyl chloride and L-histidine.A series of amide monomers were synthesized by amidation of methacryloyl chloride with amines and grafted onto commercial poly(ether sulfone) (PES) membranes using irradiation from atmospheric pressure plasma (APP).Reaction of methacryloyl chloride with the hydroxyl groups on the surfaces of HEMA/NVP microspheres was performed, leading to the introduction of polymerisable double bonds onto the surfaces of microspheres.Star-shaped poly(d,l-lactide) oligomers with 2, 3 and 6 arms were synthesised, end-functionalised with methacryloyl chloride and photo-crosslinked in the presence of ethyl lactate as a non-reactive diluent.

Specifications

CAS 920-46-7
Density 1.07 g/mL (at 25°C)
Boiling Point 95°C to 96°C
Molecular Formula C4H5ClO
Refractive Index n20/D 1.442 (literature)
Linear Formula CH2=C(CH3)COCl
Quantity 100 mL
MDL Number MFCD00000716
Synonym alpha-Methylacryloyl chloride; 2-Methyl-2-propenoyl chloride; 2-Methylacryloyl chloride; 2-Methylpropenoic acid chloride; Methacrylic acid chloride; Methacrylic chloride
Molecular Weight (g/mol) 104.53
Percent Purity 97%
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