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  7. Methylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal™ bottles

Methylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal™ bottles

Catalog No. AA41252AE
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AA41252AE 100 mL
AA41252AP 500 mL
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Catalog No. AA41252AE Supplier Thermo Scientific Chemicals Supplier No. 041252AE

Description

CAS: 75-16-1 | CH3BrMg | 119.24 g/mol

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Methylmagnesium bromide, 3M in ether has the wide range of applications in organic synthesis. Alkylation of aldehydes and ketones is the most common applications of Grignard reagent. It is a strong nucleophile that can form new carbon-carbon bonds. Also like organolithium compounds, it is useful to form carbon-heteroatom bonds.

Solubility
Soluble in ether, toluene and tetrahydrfuran. Insoluble in hydrocarbons.

Notes
It is highly flammable and reacts with moisture or water to form methane gas, so it should be stored in tightly closed containers.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 75-16-1
Molecular Formula CH3BrMg
Molecular Weight (g/mol) 119.24
MDL Number MFCD00000041
InChI Key AVFUHBJCUUTGCD-UHFFFAOYSA-M
PubChem CID 6349
SMILES C[Mg]Br

Specifications

Color Brown
Physical Form Liquid
Quantity 100 mL
Linear Formula CH3MgBr
UN Number UN1928
Flash Point -40°C (-40°F)
Synonym methylmagnesium bromide, methyl magnesium bromide, magnesium, bromomethyl, bromo methyl magnesium, methylmagnesium bromide solution, 3.0 m in diethyl ether, unii-22cw9773df, memgbr, methymagnesiumbromide, ch3mgbr, methylmagnesiumbromide, grignard reagent
IUPAC Name magnesium;carbanide;bromide
Formula Weight 119.26
Concentration or Composition (by Analyte or Components) 3M in ether
Odor Ether-like
Packaging ChemSeal™ bottles
Sensitivity Air and moisture sensitive
Density 1.035 g/mL
Chemical Name or Material Methylmagnesium bromide
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Safety and Handling

Hazard Category H224-H260-H302-H314-H318-H335-H336
Hazard Statement GHS H Statement
H224-H261-H314-H318-H302-H336
Extremely flammable liquid and vapor.
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
Causes serious eye damage.
Harmful if swallowed.
May cause drowsiness or dizziness.
Precautionary Statement P210-P231+P232-P233-P240-P241-P242-P243-P261-P264b-P270-P271-P280-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P310-P312-P330-P331-P363-P372-P374-P380-P501c
DOTInformation Transport Hazard Class: 4.3; Packaging Group: I; Proper Shipping Name: METHYL MAGNESIUM BROMIDE, IN ETHYL ETHER
EINECSNumber 200-844-1
TSCA Yes
storageNote1
  • Packaged under Argon
Recommended Storage Ambient temperatures; Store under Argon
SDS

RUO – Research Use Only

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