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Sigma Aldrich N-Hydroxytetrachlorophthalimide

Catalog No. ALD0056450G Shop All MilliporeSigma Sigma Organic Chemistry Products
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MilliporeSigma Sigma Organics products encompass a wide range of quality reagents, solvents, catalysts, and building blocks for organic synthesis. From benchtop discovery to process development and scale-up, Sigma Organics solutions are built to meet the needs of synthetic chemists.

N-Hydroxytetrachlorophthalimide (TCNHPI) is an aryl-tetrahalogenated N-hydroxyphthalimide derivative. In combination with 1,4-diamino-2,3-dichloroanthraquinone (DADCAQ), it forms an efficient catalytic system for the oxidation of aromatic hydrocarbons using molecular oxygen under metal-free and aerobic conditions.New reagent enabling the electrochemical allylic C-H oxidation reaction developed by the Baran group. This method provides a scalable and sustainable alternative to current strategies based on toxic reagents or precious metals.Electrochemical Allylic C–H Oxidation with N-Hydroxytetrachlorophthalimide (TCNHPI)Scalable and sustainable electrochemical allylic C–H oxidationA general alkyl-alkyl cross-coupling enabled by redox-active esters and alkylzinc reagentsNickel-Catalyzed Cross-Coupling of Redox-Active Esters with Boronic AcidsPractical Ni-Catalyzed Aryl-Alkyl Cross-Coupling of Secondary Redox-Active Esters

Specifications

CAS 85342-65-0
Molecular Formula C8HCl4NO3
Linear Formula C8HCl4NO3
Quantity 1 g
Synonym 4,5,6,7-Tetrachloro-2-hydroxy-1H-isoindole-1,3(2H)-dione; Tetrachloro-N-hydroxyphthalimide
Molecular Weight (g/mol) 300.91 g/mol
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