Sigma Aldrich Phenylmagnesium Bromide Solution

Catalog No. 17-156-5800ML

Supplier: Sigma Aldrich 171565800ML

Description

MilliporeSigma Sigma Organics products encompass a wide range of quality reagents, solvents, catalysts, and building blocks for organic synthesis. From benchtop discovery to process development and scale-up, Sigma Organics solutions are built to meet the needs of synthetic chemists.

Phenylmagnesium bromide solution contains 3M phenylmagnesium bromide in diethyl ether. It can act as a strong acid and Lewis acid. It can undergo addition reaction with many unsaturated functional groups. The phenyl group can displace halide from other organic compounds. Phenylmagnesium bromide is a Grignard reagent. Reaction of +a-cyclohexanedione (dihydroresorcinol) with phenylmagnesium bromide has been investigated.Phenylmagnesium bromide was used for the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s. It was also used for the monoalkylation of aliphatic primary amine to generate secondary amines by the Grignard reaction of 1-[(alkylamino) methyl] benzotriazoles. It may be used for synthesis of the following: 1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol 6-benzyl-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-ol (3-(2-Dithiobenzoatepropionyl)propyl)dimethylmethoxysilane, reversible addition-fragmentation chain transfer polymerization (RAFT)-silane agent series of o-substituted benzophenonesStorage below 25°C may cause formation of crystalline magnesium salts. Moving container to a war mLocation and occasional gentle swirling should redissolve the solid

Specifications

• CAS: 100-58-3
• Density: 1.134 g/mL at 25°C
• Molecular Formula: C6H5BrMg
• Linear Formula: C6H5MgBr
• MDL Number: MFCD00000038
• Quantity: 800 mL
• Molecular Weight (g/mol): 181.31 g/mol
• Biological Activity: Central Nervous System