Phenylselenenyl bromide, 98%

Description

CAS: 34837-55-3 | C6H5BrSe | 235.981 g/mol

Employed in the synthesis of enones by selenenylation of α-cyano ketones with lithium naphthalenide. Phenylselenyl bromide was used in the preparation of exo-2-methyl-7-phenylselenyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione and endo-2-methyl-7-phenylselanyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Employed in the synthesis of enones by selenenylation of α-cyano ketones with lithium naphthalenide. Phenylselenyl bromide was used in the preparation of exo-2-methyl-7-phenylselenyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione and endo-2-methyl-7-phenylselanyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione.

Solubility
Soluble in toluene, very faint turbidity.

Notes
Moisture Sensitive. Store away from air and water/moisture. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Specifications

Chemical Identifiers

• CAS: 34837-55-3
• Molecular Formula: C6H5BrSe
• Molecular Weight (g/mol): 235.981
• MDL Number: MFCD00000047
• InChI Key: LCEFEIBEOBPPSJ-UHFFFAOYSA-N
• Synonym: phenylselenyl bromide, benzeneselenenyl bromide, phenylselenenyl bromide, bromoselenobenzene, phsebr, phenylselenylbromide, benzeneselenyl bromide, phenylselanyl bromane, brseph, phenylseleno bromide
• PubChem CID: 123446
• IUPAC Name: phenyl selenohypobromite
• SMILES: C1=CC=C(C=C1)[Se]Br

• Melting Point: 56°C to 62°C
• Boiling Point: 107°C to 108°C (15 mmHg)
• Quantity: 1 g
• UN Number: UN2928
• Beilstein: 2039772
• Sensitivity: Moisture sensitive
• Solubility Information: Soluble in toluene,very faint turbidity.
• Formula Weight: 235.98
• Percent Purity: 98%
• Chemical Name or Material: Phenylselenenyl bromide

Safety and Handling

Hazard Category	H301+H331-H314-H373
Hazard Statement	GHS H Statement H301-H331-H373 Toxic if swallowed. Toxic if inhaled. May cause damage to organs through prolonged or repeated exposure.
Precautionary Statement	P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P501c
DOTInformation	Transport Hazard Class: 6.1; Packing Group: II; Proper Shipping Name: TOXIC SOLIDS, CORROSIVE, ORGANIC, N.O.S.
EINECSNumber	252-238-1
TSCA	No
Recommended Storage	Ambient temperatures

SDS

RUO – Research Use Only