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(R)-2-Methyl-CBS-oxazaborolidine, 1M soln. in toluene

Catalog No. AAL14582AA
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Quantity:
5 mL
25 mL

CAS: 112022-83-0 | C18H20BNO | 277.17 g/mol

(R)-2-Methyl-CBS-oxazaborolidine is used in the asymmetric reduction of prochiral ketones. Other applications include the enantioselective synthesis of α-hydroxy acids, α-amino acids, C2 symmetrical ferrocenyl diols, and propargyl alcohols. It is also used in a desymmetrizing reduction leading to (S)-4-hydroxycyclohexenone. It is useful in the production of stereospecific motifs such as α-hydroxy acids, α-amino acids, symmetrical ferrocenyl diols and propargyl alcohols.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(R)-2-Methyl-CBS-oxazaborolidine is used in the asymmetric reduction of prochiral ketones. Other applications include the enantioselective synthesis of α-hydroxy acids, α-amino acids, C2 symmetrical ferrocenyl diols, and propargyl alcohols. It is also used in a desymmetrizing reduction leading to (S)-4-hydroxycyclohexenone. It is useful in the production of stereospecific motifs such as α-hydroxy acids, α-amino acids, symmetrical ferrocenyl diols and propargyl alcohols.

Solubility
Not miscible or difficult to mix in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store under inert gas. It is sensitive to moisture and air. Incompatible with oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 112022-83-0
Molecular Formula C18H20BNO
Molecular Weight (g/mol) 277.17
MDL Number MFCD00078440
InChI Key VMKAFJQFKBASMU-QGZVFWFLSA-N
Synonym r-2-methyl-cbs-oxazaborolidine, r-methyl oxazaborolidine, r-+-2-methyl-cbs-oxazaborolidine, r-5,5-diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine, r-1-methyl-3,3-diphenylhexahydropyrrolo 1,2-c 1,3,2 oxazaborole, r-me-cbs catalyst, r-3,3-diphenyl-1-methylpyrrolidino 1,2-c-1,3,2-oxazaborole, r-me cbs, r-tetrahydro-1-methyl-3,3-diphenyl-1h,3h-pyrrolo 1,2-c 1,3,2 oxazaborole, corey's catalyst
PubChem CID 9838490
IUPAC Name (3aR)-1-methyl-3,3-diphenyl-3a,4,5,6-tetrahydropyrrolo[1,2-c][1,3,2]oxazaborole
SMILES [H][C@]12CCCN1B(C)OC2(C1=CC=CC=C1)C1=CC=CC=C1

Specifications

Density 0.925
Flash Point 4°C (39°F)
Quantity 5 mL
UN Number UN1993
Sensitivity Air and moisture sensitive
Solubility Information Not miscible or difficult to mix in water.
Formula Weight 277.17
Concentration or Composition (by Analyte or Components) 1M soln. in toluene
Chemical Name or Material (R)-2-Methyl-CBS-oxazaborolidine
missing translation for 'healthHazard1' H225-H302-H304-H315-H318-H335-H336-H361d-H372
missing translation for 'healthHazard2' GHS H Statement
H225-H304-H361-H373-H315-H336
Highly flammable liquid and vapor.
May be fatal if swallowed and enters airways.
Suspected of damaging fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.
Causes skin irritation.
May cause drowsiness or dizziness.
missing translation for 'healthHazard3' P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P281-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P308+P313-P310-P330-P331-P332+P313-P363-P370+P378q-P50
DOTInformation Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
TSCA No
Recommended Storage Ambient temperatures; Store under Argon

RUO – Research Use Only

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