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Rhodium(II) acetate, dimer, 98+%

Catalog No. AAL15152ME
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Catalog No. AAL15152ME Supplier Thermo Scientific Chemicals Supplier No. L15152ME
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Description

CAS: 15956-28-2 | C8H12O8Rh2 | 441.99 g/mol

Catalyst for cyclopropanation of alkenes, oxidation of alcohols, cyclization reactions involving ?-diazo carbonyl groups, insertion into C-H and X-H bonds (X-H is NH or SH or OH) and for ylide formation. More reactive and useful in differentiating ribonucleosides and deoxynucleosides. It is also used in functionalizing fullerenes into polymers. Efficient catalyst for hydrogen transfer from 2-propanol to cyclohexanone and other unsaturated compounds.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Catalyst for cyclopropanation of alkenes, oxidation of alcohols, cyclization reactions involving ɑ-diazo carbonyl groups, insertion into C-H and X-H bonds (X-H is NH or SH or OH) and for ylide formation. More reactive and useful in differentiating ribonucleosides and deoxynucleosides. It is also used in functionalizing fullerenes into polymers. Efficient catalyst for hydrogen transfer from 2-propanol to cyclohexanone and other unsaturated compounds.

Solubility
Soluble in aqueous solution like water. Slightly soluble in ethanol

Notes
Stable under normal conditions.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 15956-28-2
Molecular Formula C8H12O8Rh2
Molecular Weight (g/mol) 441.99
MDL Number MFCD00003538
InChI Key VOXKIADTKKPBBP-UHFFFAOYSA-N
Synonym rhodium ii acetate, rhodium diacetate, acetic acid, rhodium 2+ salt, rhodium ii acetate dimer dihydrate, dirhodium tetraacetate, rhodium ii acetate dimer, rhodium acetate, brown, water soluble, diacetoxyrhodium
PubChem CID 122130469
SMILES C[C-]1O[Rh++]234O[C-](C)O[Rh++]2(O1)(O[C-](C)O3)O[C-](C)O4

Specifications

Melting Point 205°C
Quantity 500 mg
Linear Formula [Rh(CO2CH3)2]2
Solubility Information Soluble in aqueous solution like water. Slightly soluble in ethanol
IUPAC Name tetramethyl-2,4,6,8,9,11,12,14-octaoxa-1,5-dirhodatetracyclo[3.3.3.3¹,⁵.0¹,⁵]tetradecane-1,1,5,5-tetrakis(ylium)-3,7,10,13-tetraide
Formula Weight 441.99
Percent Purity ≥98%
Odor Odorless
Chemical Name or Material Rhodium(II) acetate, dimer

Safety and Handling

Hazard Category H315-H319
Precautionary Statement P264b-P280-P302+P352-P305+P351+P338-P332+P313-P362
EINECSNumber 240-084-8
RTECSNumber VI9361000
TSCA No
Recommended Storage Ambient temperatures; Store under Nitrogen
SDS

RUO – Research Use Only

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