Ruthenium(III) 2,4-pentanedionate, Ru 24% min

Description

For Hydrogenation | CAS: 14284-93-6 | C15H21O6Ru | 398.40 g/mol

Precursor for the preparation of other compounds of ruthenium. Ruthenium(III) 2,4-pentanedionate is employed as a recyclable catalyst for certain organic transformations like the acetylation of phenols, alcohols, and amines under neat conditions. It is also used as a homogeneous catalyst, for example, in the hydrolysis of sodium borohydride and regiospecific tritiation of aromatic carboxylic acids. It is also used as a catalyst for enantioselective hydrogenation of acids such as aryl acrylic acid and aryl propenic acid.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

• CAS: 14284-93-6
• Molecular Formula: C15H21O6Ru
• Molecular Weight (g/mol): 398.40
• MDL Number: MFCD00000030
• InChI Key: RTZYCRSRNSTRGC-LNTINUHCSA-K
• Synonym: ruthenium acetylacetonate, ruthenium iii acetylacetonate, acetylacetone ruthenium iii salt, tris 2,4-pentanedionato ruthenium iii, tris pentane-2,4-dionato-o,o' ruthenium, ruthenium, tris 2,4-pentanedionato-o,o'-, oc-6-11, ruthenium, tris 2,4-pentanedionato-kappao,kappao'-, oc-6-11, ruthenium, tris 2,4-pentanedionato-8ci, z-4-oxopent-2-en-2-olate; ruthenium 3+
• PubChem CID: 5488829
• SMILES: [Ru+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O

• Melting Point: 260°C (decomposition)
• Color: White
• Physical Form: Crystalline
• Quantity: 5 g
• Solubility Information: Soluble in most organic solvents such as acetone,chlorinated hydrocarbons,alcohols,cyclohexane and benzene. Insoluble in water.
• IUPAC Name: ruthenium(3+) tris((2Z)-4-oxopent-2-en-2-olate)
• Formula Weight: 398.4
• Appearance: Red crystals
• Chemical Name or Material: Ruthenium(III) 2, 4-pentanedionate, Ru 24% min.

Safety and Handling

Hazard Category	H315-H319-H335
Precautionary Statement	P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
EINECSNumber	238-193-0
TSCA	Yes
Recommended Storage	Ambient temperatures

SDS

RUO – Research Use Only