(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 98+%

Description

CAS: 35193-64-7 | C20H13O4P | 348.294 g/mol

Used as a chiral Bronsted acid catalyst in the enantoselective Mannich reaction.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Used as a chiral Bronsted acid catalyst in the enantoselective Mannich reaction.

Solubility
Soluble in DMSO and methanol (hot).

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agents.

Specifications

Chemical Identifiers

• CAS: 35193-64-7
• Molecular Formula: C20H13O4P
• Molecular Weight (g/mol): 348.294
• MDL Number: MFCD00010045
• InChI Key: JEHUZVBIUCAMRZ-UHFFFAOYSA-N
• Synonym: 1,1'-binaphthyl-2,2'-diyl hydrogenphosphate, s-+-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate, r---1,1'-binaphthyl-2,2'-diyl hydrogenphosphate, 1,1'-binaphthyl-2,2'-diyl hydrogen phosphate, r---bnp acid, 11bs-4-hydroxydinaphtho 2,1-d:1',2'-f 1,3,2 dioxaphosphepine 4-oxide, r---1,1'-binaphthyl-2,2'-diyl hydrogen phosphate, r-4-hydroxydinaphtho 2,1-d:1',2'-f 1,3,2 dioxaphosphepine 4-oxide, s-+-bnp acid, 4-hydroxydinaphtho 2,1-d:1',2'-f 1,3,2 dioxaphosphepine 4-oxide
• PubChem CID: 99589
• SMILES: C1=CC=C2C(=C1)C=CC3=C2C4=C(C=CC5=CC=CC=C54)OP(=O)(O3)O

• Melting Point: >300°C
• Quantity: 5 g
• Beilstein: 4787775
• Solubility Information: Soluble in DMSO and methanol (hot).
• Optical Rotation: +605° (c=1 in Methanol)
• Formula Weight: 348.3
• Percent Purity: ≥98%
• Chemical Name or Material: (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate

Safety and Handling

Hazard Category	H315-H319-H335
Hazard Statement	GHS H Statement H315-H319-H335 Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statement	P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
TSCA	No
Recommended Storage	Ambient temperatures

SDS

RUO – Research Use Only