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Sigma Aldrich Slap N-Bn-3Me-Pip Reagent

Catalog No. 900406500MG Shop All MilliporeSigma Sigma Organic Chemistry Products
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90-040-6500MG 250 mg
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Description

MilliporeSigma Sigma Organics products encompass a wide range of quality reagents, solvents, catalysts, and building blocks for organic synthesis. From benchtop discovery to process development and scale-up, Sigma Organics solutions are built to meet the needs of synthetic chemists.

Silicon amine protocol (SLAP) reagents, in conjunction with aldehydes and ketones, form N-unprotected piperazines via photocatalytic cross-coupling with Ir[(ppy)2dtbbpy]PF6 (747769). Heteroaromatic, aromatic, and aliphatic aldehydes are well tolerated, as are structurally and stereochemically complex SLAP reagents. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents for piperazine synthesis.Technology Spotlight: SLAP Reagents for Piperazine SynthesisSilicon Amine Reagents for the Photocatalytic Synthesis of Piperazines from Aldehydes and KetonesLewis Acid Induced Toggle from Ir(II) to Ir(IV) Pathways in Photocatalytic Reactions: Synthesis of Thiomorpholines and Thiazepanes from Aldehydes and SLAP Reagents.Continuous Flow Synthesis of Morpholines and Oxazepanes with Silicon Amine Protocol (SLAP) Reagents and Lewis Acid Facilitated Photoredox Catalysis

Specifications

CAS 1902911-45-8
Molecular Formula C37H41ClNiO3P2
Linear Formula C37H41ClNiO3P2
Quantity 250 mg
Molecular Weight (g/mol) 689.81 g/mol
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