Sigma Aldrich Super-Hydride™ Solution

Catalog No. 17-972-88L

Supplier: Sigma Aldrich 1797288L

Description

MilliporeSigma Sigma Organics products encompass a wide range of quality reagents, solvents, catalysts, and building blocks for organic synthesis. From benchtop discovery to process development and scale-up, Sigma Organics solutions are built to meet the needs of synthetic chemists.

Super-Hydride™ solution (Lithium triethylborohydride or LiTEBH) is widely used as a powerful and selective reducing agent that shows super hydride activity in organic synthesis.LiTEBH can be used as a reagent: To reduce alkyl halides to alkanes via dehydrogenation reactions.For the selective reduction of epoxides to Markovnikov alcohols. To reduce tosylates or mesylates primary alcohols to hydrocarbons.For reductive cyclization reactions for the preparation of useful intermediates.In the synthesis of hepta(manno-3-deoxy-6-O-t-butyldimethylsilyl)-+a-cyclodextrin by reduction of hepta(manno-2,3-anhydro-6-O-t-butyldimethylsilyl)-+a-cyclodextrin.For hydrodefluorination of C-F bonds using Ni catalyst.To prepare alkynyl alcohols from cleavage of cyclic keto-vinyl triflates.In the stereoselective reduction of bicyclic imides, isoquinolines, and pyridines.To prepare tungsten and molybdenum hydride complexes.Super-Hydride is a registered trademark of Sigma-Aldrich Co. LLC

Specifications

• CAS: 22560-16-3
• Density: 0.892 g/mL at 25°C
• Molecular Formula: C6H16BLi
• Linear Formula: Li(C2H5)3BH
• MDL Number: MFCD00011703
• Quantity: 8 L
• Synonym: Lithium triethylborohydride solution
• Molecular Weight (g/mol): 105.94 g/mol
• Biological Activity: Respiratory System