Sigma Aldrich Thianthrene S-Oxide

Catalog No.	Quantity
90-397-35G	1 g
90-397-31G	250 mg

Catalog No. 90-397-35G

Supplier: Sigma Aldrich 9039735G

Description

MilliporeSigma Sigma Organics products encompass a wide range of quality reagents, solvents, catalysts, and building blocks for organic synthesis. From benchtop discovery to process development and scale-up, Sigma Organics solutions are built to meet the needs of synthetic chemists.

Thianthrene S-oxide is a sulfoxide-based thianthrene reagent for late-stage C-H functionalization. Developed by the Ritter Lab, C-H functionalization by thianthrenation proceeds with >99% selectivity and furnishes functionalized arenes serving as synthetic linchpins for further participation in diverse transformations. Nonfluorinated thianthrene S-oxide is best used for all arenes more electron-rich than anisole. For other arenes, the fluorinated TFT S-oxide (903981) was demonstrated as the thanthrenation reagent.Site-selective and versatile aromatic C-H functionalization by thianthrenationVideo: Site-selective C-H functionalization by thianthrenationIn the Pipeline: New Chemistry, Making New ThingsTi(Phen)(OC2H5)2Cl2: a highly efficient pre-?catalyst for selective oxidation of organic sulfides to sulfoxides by hydrogen peroxidePatent Application EP18204755.5 This product is manufactured pursuant to a license with Studiengesellschaft Kohle mbH

Specifications

• CAS: 23570-43-6
• Molecular Formula: C12H8OS2
• Linear Formula: C12H8OS2
• MDL Number: MFCD01464038
• Quantity: 1 g
• Synonym: Non-fluorinated sulfoxide-based thianthrene reagent; Thianthrene 5-oxide
• Molecular Weight (g/mol): 232.32 g/mol