Sigma Aldrich Trichlorosilane

Catalog No.	Quantity
17-555-25G	5 g
17-555-2500G	500 g
17-555-2100G	100 g

Catalog No. 17-555-25G

Supplier: Sigma Aldrich 1755525G

Description

MilliporeSigma Sigma Organics products encompass a wide range of quality reagents, solvents, catalysts, and building blocks for organic synthesis. From benchtop discovery to process development and scale-up, Sigma Organics solutions are built to meet the needs of synthetic chemists.

Trichlorosilane is generally used for the asymmetric hydrosilylation of olefins in the presence of palladium catalysts coordinated with chiral monodentate phosphorus ligands to generate chiral organosilanes.Trichlorosilane has been used to synthesize 11-dicyclohexylphosphino-12-phenyl-9,10-dihydro-9,10-ethenoanthracene (H-KITPHOS) via reduction of 11-dicyclohexylphosphinoyl-12-phenyl-9,10-dihydro-9,10-ethenoanthracene.Other possible applications:Asymmetric reduction of N-aryl ketimines in the presence of a novelL-valine-derived catalyst to form secondary amines.Hydrosilylation of imidazolinones to form chiral imidazolidinones in the presence of a 2,2'sa-bispyrrolidine based Lewis base organocatalyst.Trichlorosilane activated with chiral N-formylprolinederivatives is an effective reagent for the reduction of imines to formenantiomerically enriched amines.Trichlorosilane reacts with dimethylformamide to form hypervalent hydridosilicates, which can reduce aldehydes to alcohols, imines to amines, and also for the reductive amination of aldehydes.

Specifications

• CAS: 10025-78-2
• Density: 1.342 g/mL at 25°C
• Boiling Point: 32°C to 34°C
• Molecular Formula: HCl3Si
• Linear Formula: SiHCl3
• MDL Number: MFCD00011518
• Quantity: 5 g
• Molecular Weight (g/mol): 135.45 g/mol
• Biological Activity: Respiratory System