Triethylborane, 1M soln. in THF

Description

CAS: 97-94-9 | C6H15B | 98.00 g/mol

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Triethylborane is catalyst for allylation of aldehydes, decarboxylative C-C bond cleavage reactions, rhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenations, Regioselective hydroxyalkylation of unsaturated oxime ethers. Reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes and synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential.

Solubility
Reacts with water.

Notes
Air Sensitive, store away form air. Store in cool. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Specifications

Chemical Identifiers

• CAS: 97-94-9
• Molecular Formula: C6H15B
• Molecular Weight (g/mol): 98.00
• MDL Number: MFCD00009022
• InChI Key: LALRXNPLTWZJIJ-UHFFFAOYSA-N
• Synonym: triethylboron, borane, triethyl, triethylborine, boron triethyl, boron ethyl, unii-z3s980z4p3, hsdb 897, triethylboran, borethyl, triethyl borane
• PubChem CID: 7357
• IUPAC Name: triethylborane
• SMILES: CCB(CC)CC

• Density: 0.865
• Flash Point: −17°C (1°F)
• Linear Formula: (CH₃CH₂)₃B
• Quantity: 100 mL
• UN Number: UN2924
• Beilstein: 1731462
• Sensitivity: Air Sensitive
• Solubility Information: Reacts with water.
• Formula Weight: 98
• Concentration or Composition (by Analyte or Components): 1M soln. in THF
• Chemical Name or Material: Triethylborane

Safety and Handling

Hazard Category	H225-H302+H332-H314-H335-H336-H351
Hazard Statement	GHS H Statement H225-H314-H318 Highly flammable liquid and vapor. Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statement	P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c
DOTInformation	Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, CORROSIVE, N.O.S.
EINECSNumber	202-620-9
RTECSNumber	ED2100000
TSCA	Yes
Recommended Storage	Ambient temperatures; Store under Argon

SDS

RUO – Research Use Only