Tris[N,N-bis(trimethylsilyl)amide]cerium(III), 98%, Thermo Scientific Chemicals

Description

Tris[N,N-bis(trimethylsilyl)amide]cerium(III) is used as a reactant for synthesis of amidocerium(IV) oxides, Sterically encumbered N-heterocyclic carbene ligands, Lanthanide imidodiphosphinate complexes with electroluminescent properties, Lanthanide complexes of an oxazoline-phenoxide hybrid chelate. Some of the other applications include it is used as a reactant for One-electron oxidation to produce tetravalent cerium compounds, Addition-elimination reactions across the M-C bond of metal N-heterocyclic carbenes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

• CAS: 41836-21-9
• Molecular Formula: C18H54CeN3Si6
• Molecular Weight (g/mol): 621.277
• MDL Number: MFCD03411241
• InChI Key: DPCZDYUESIKMSU-UHFFFAOYSA-N
• Synonym: bis trimethylsilyl azanide; cerium 3+, tris bis trimethylsilyl amino cerium iii, cerium 3+ tris bis trimethylsilyl azanide, tris n,n-bis trimethylsilyl amide cerium iii , 96 %
• PubChem CID: 6093781
• IUPAC Name: bis(trimethylsilyl)azanide;cerium(3+)
• SMILES: C[Si](C)(C)[N-][Si](C)(C)C.C[Si](C)(C)[N-][Si](C)(C)C.C[Si](C)(C)[N-][Si](C)(C)C.[Ce+3]

• Color: Yellow
• Linear Formula: [[(CH₃)₃Si]₂N]₃Ce
• Quantity: 25 g
• UN Number: UN3396
• Sensitivity: Moisture sensitive
• Solubility Information: Soluble in water,protic solvents.
• Formula Weight: 621.27
• Percent Purity: 98%
• Physical Form: Powder
• Chemical Name or Material: Tris[N,N-bis (trimethylsilyl)amide]cerium (III)

Safety and Handling

Hazard Category	H228-H261-H314-H335
Hazard Statement	GHS H Statement H261-H228-H314-H318 In contact with water releases flammable gas. Flammable solid. Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statement	P210-P223-P231+P232-P240-P241-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P335+P334-P363-P370+P378q-P501c
DOTInformation	Transport Hazard Class: 4.3; Packing Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, FLAMMABLE
TSCA	No
Recommended Storage	Ambient temperatures

SDS

RUO – Research Use Only