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Sigma Aldrich Tris(Trimethylsilyl)Silanol

Catalog No. 9024895G Shop All MilliporeSigma Sigma Organic Chemistry Products
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250 mg
5 g
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90-248-95G 250 mg
90-248-91G 5 g
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Description

MilliporeSigma Sigma Organics products encompass a wide range of quality reagents, solvents, catalysts, and building blocks for organic synthesis. From benchtop discovery to process development and scale-up, Sigma Organics solutions are built to meet the needs of synthetic chemists.

Under a dual catalytic copper/photoredox manifold, this supersilanol has been demonstrated by the MacMillan lab to be an excellent reagent for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. To be use in conjunction with dMesSCF3 (901466) and Ir photocatalyst (902217 or 902225).A radical approach to the copper oxidative addition problem: Trifluoromethylation of bromoarenes

Specifications

CAS 2021255-91-2
Molecular Formula C61H60FeNO3PPdS
Refractive Index n/D 1.496
Linear Formula C61H60FeNO3PPdS
MDL Number MFCD12911997
Quantity 250 mg
Synonym QPhos G3 Palladacycle; QPhos Palladacycle
Molecular Weight (g/mol) 1080.44 g/mol
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