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Sigma Aldrich Zirconium(IV) chloride

Catalog No. 357405100G Shop All MilliporeSigma Sigma Organic Chemistry Products
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35-740-5100G 100 g
35-740-510G 10 g
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Description

MilliporeSigma Sigma Organics products encompass a wide range of quality reagents, solvents, catalysts, and building blocks for organic synthesis. From benchtop discovery to process development and scale-up, Sigma Organics solutions are built to meet the needs of synthetic chemists.

Zirconium (IV) chloride acts as an efficient Lewis acid catalyst for various reactions; such as:electrophilic addition reaction of indole with aldehydes/ketones to form bis(indolyl)methanes. electrophilic amination of activated arenes,transthioacetylization of acetals,deoxygenation of heterocyclic-N-oxides,reduction of nitro compounds,conversion of carbonyl compounds to 1,3-oxathiolanes,Biginelli reaction for the synthesis of 3,4-dihydropyrimidin-2(1H)-ones,direct amide coupling of non activated carboxylic acids and amines,synthesis of quinoxalines and pyrido[2,3-b]pyrazines,deprotection of t-butyldimethylsilyl (TBDMS) ethers.Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the correspondingα,α-dimethylamines.

Specifications

CAS 10026-11-6
Density 2.8 g/mL (at 25°C)
Molecular Formula Cl4Zr
Linear Formula ZrCl4
MDL Number MFCD00011306
Quantity 100 g
Synonym Tetrachlorozirconium; Zirconium tetrachloride
Molecular Weight (g/mol) 233.04
Percent Purity ≥99.9% trace metals basis
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