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  6. 1,1'-Bis(diisopropylphosphino)ferrocene, 98%, Thermo Scientific Chemicals

1,1'-Bis(diisopropylphosphino)ferrocene, 98%, Thermo Scientific Chemicals

Catalog No. AAH2705703
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AAH2705706 5 g
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Description

The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1′-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.

Solubility
Insoluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 97239-80-0
Molecular Formula C22H36FeP2
Molecular Weight (g/mol) 418.32
MDL Number MFCD02684559
IUPAC Name 1,1'-Bis(diisopropylphosphino)ferrocene
SMILES [Fe].CC(C)P(C(C)C)c1cccc1.CC(C)P(C(C)C)c1cccc1

Specifications

Melting Point 50°C to 52°C
Flash Point >110°C (230°F)
Quantity 1 g
Solubility Information Insoluble in water.
Formula Weight 418.34
Percent Purity 98%
Chemical Name or Material 1,1'-Bis(diisopropylphosphino)ferrocene

Safety and Handling

Hazard Category H302-H315-H319-H335
Precautionary Statement P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c
TSCA No
Recommended Storage Ambient temperatures
SDS

RUO – Research Use Only

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