1,1'-Bis(diisopropylphosphino)ferrocene, 98%, Thermo Scientific Chemicals

Description

The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1′-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.

Solubility
Insoluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Specifications

Chemical Identifiers

• CAS: 97239-80-0
• Molecular Formula: C22H36FeP2
• Molecular Weight (g/mol): 418.32
• MDL Number: MFCD02684559
• IUPAC Name: 1,1'-Bis(diisopropylphosphino)ferrocene
• SMILES: [Fe].CC(C)P(C(C)C)c1cccc1.CC(C)P(C(C)C)c1cccc1

• Melting Point: 50°C to 52°C
• Flash Point: >110°C (230°F)
• Quantity: 1 g
• Solubility Information: Insoluble in water.
• Formula Weight: 418.34
• Percent Purity: 98%
• Chemical Name or Material: 1,1'-Bis(diisopropylphosphino)ferrocene

Safety and Handling

Hazard Category	H302-H315-H319-H335
Precautionary Statement	P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c
TSCA	No
Recommended Storage	Ambient temperatures

SDS

RUO – Research Use Only