1-(Triisopropylsilyl)pyrrole, 95%

Description

CAS: 87630-35-1 | C13H25NSi | 223.44 g/mol

1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate; heterocyclic base, 3-nitropyrrole and 3-nitropyrrole, required for the synthesis of 1 -(2?-deoxy-β-D-ribofuranosyl)-3-nitropyrrole. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate; heterocyclic base, 3-nitropyrrole and 3-nitropyrrole, required for the synthesis of 1 -(2′-deoxy-β-D-ribofuranosyl)-3-nitropyrrole. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).

Solubility
Not miscible in water.

Notes
Moisture sensitive. Incompatible with oxidizing agents.

Specifications

Chemical Identifiers

• CAS: 87630-35-1
• Molecular Formula: C13H25NSi
• Molecular Weight (g/mol): 223.44
• MDL Number: MFCD00054932
• InChI Key: FBQURXLBJJNDBX-UHFFFAOYSA-N
• Synonym: 1-triisopropylsilyl pyrrole, 1-triisopropylsilyl-1h-pyrrole, n-triisopropylsilylpyrrole, 1h-pyrrole, 1-tris 1-methylethyl silyl, tri propan-2-yl-pyrrol-1-ylsilane, 1-tris propan-2-yl silyl-1h-pyrrole, pubchem9194, 1-triisopropylsilylpyrrole, 1-triisoproylsilyl-pyrrole, acmc-1bkd7
• PubChem CID: 145136
• IUPAC Name: tri(propan-2-yl)-pyrrol-1-ylsilane
• SMILES: CC(C)[Si](C(C)C)(C(C)C)N1C=CC=C1

• Density: 0.904
• Boiling Point: 78°C (0.4 mmHg)
• Flash Point: 106°C (222°F)
• Refractive Index: 1.492
• Quantity: 25 g
• Beilstein: 3540663
• Sensitivity: Moisture sensitive
• Solubility Information: Not miscible in water.
• Formula Weight: 223.44
• Percent Purity: 95%
• Chemical Name or Material: 1-(Triisopropylsilyl)pyrrole

Safety and Handling

Hazard Category	H302+H332-H319
Hazard Statement	GHS H Statement H302 Harmful if swallowed.
Precautionary Statement	P261-P264b-P270-P271-P280i-P301+P312-P304+P340-P305+P351+P338-P312-P330-P501c
TSCA	No
Recommended Storage	Ambient temperatures

SDS

RUO – Research Use Only