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4-Nitrocinnamaldehyde, predominantly trans, 98%, Thermo Scientific™

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Quantity:
5g
25g
50g
1734-79-8
C9H7NO3
177.159
MFCD00007379
ALGQVMMYDWQDEC-OWOJBTEDSA-N
4-nitrocinnamaldehyde, 3-4-nitrophenyl acrylaldehyde, p-nitrocinnamaldehyde, 2-propenal, 3-4-nitrophenyl, cinnamaldehyde, p-nitro, trans-4-nitrocinnamaldehyde, e-3-4-nitrophenyl acrylaldehyde, 3-4-nitrophenyl-2-propenal, unii-48r8lam7yx, 2e-3-4-nitrophenyl prop-2-enal
5354135
(E)-3-(4-nitrophenyl)prop-2-enal
C1=CC(=CC=C1C=CC=O)[N+](=O)[O-]
1734-79-8
C9H7NO3
177.159
MFCD00007379
ALGQVMMYDWQDEC-OWOJBTEDSA-N
4-nitrocinnamaldehyde, 3-4-nitrophenyl acrylaldehyde, p-nitrocinnamaldehyde, 2-propenal, 3-4-nitrophenyl, cinnamaldehyde, p-nitro, trans-4-nitrocinnamaldehyde, e-3-4-nitrophenyl acrylaldehyde, 3-4-nitrophenyl-2-propenal, unii-48r8lam7yx, 2e-3-4-nitrophenyl prop-2-enal
5354135
(E)-3-(4-nitrophenyl)prop-2-enal
C1=CC(=CC=C1C=CC=O)[N+](=O)[O-]

 

Doebner-Miller reaction the 4- nitrocinnamaldehyde and 2-methylaniline in concentrated HC1 give the corresponding 8-methyl-2-phenylquinoline (3: R = 4'-N02) directly. The asymmetric Friedel-Crafts-type alkylation in aqueous media reaction of 4-Nitrocinnamaldehydr with N-methyl indole using trifluoroacetic acid (TFA) salt of the PEG-PS-supported prolyl peptide having the polyleucine tether as a catalyst. 4-Nitrocinnamaldehyde has been used in the preparation of 2, 2?-[(E)-3-(4-nitrophenyl) prop-2-ene-1,1-diyl] bis(3-hydroxy-5, 5-dimethylcyclohex-2-en-1-one).

This Thermo Scientific brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific.

Applications
Doebner-Miller reaction the 4- nitrocinnamaldehyde and 2-methylaniline in concentrated HC1 give the corresponding 8-methyl-2-phenylquinoline (3: R = 4′-N02) directly. The asymmetric Friedel-Crafts-type alkylation in aqueous media reaction of 4-Nitrocinnamaldehydr with N-methyl indole using trifluoroacetic acid (TFA) salt of the PEG-PS-supported prolyl peptide having the polyleucine tether as a catalyst. 4-Nitrocinnamaldehyde has been used in the preparation of 2, 2′-[(E)-3-(4-nitrophenyl) prop-2-ene-1,1-diyl] bis(3-hydroxy-5, 5-dimethylcyclohex-2-en-1-one).

Solubility
Insoluble in water.

Notes
Air Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, air.
Melting Point 138°C to 142°C
Odor Characteristic
Beilstein 1565424
Quantity 50g
Solubility Information Insoluble in water.
Sensitivity Air Sensitive
Formula Weight 177.16
Percent Purity 98%
Chemical Name or Material 4-Nitrocinnamaldehyde, predominantly trans

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

H315-H319-H335

EINECSNumber : 217-076-8

RTECSNumber : GD6650000

TSCA : Yes

Recommended Storage : Ambient temperatures

RUO – Research Use Only