Chlorodi(p-tolyl)phosphine, 95%

Description

CAS: 1019-71-2 | C14H14ClP | 248.69 g/mol

Chlorodi(p-tolyl)phosphine is used as a reactant for synthesis of palladium catalysts for C-C bond forming cross-coupling reactions, ligands for nickel(0)-catalyzed isomerization reactions, phosphinosulfonamide nickel complexes for oligomerization reactions. It is a reactant for phosphinylation reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Chlorodi(p-tolyl)phosphine is used as a reactant for synthesis of palladium catalysts for C-C bond forming cross-coupling reactions, ligands for nickel(0)-catalyzed isomerization reactions, phosphinosulfonamide nickel complexes for oligomerization reactions. It is a reactant for phosphinylation reactions.

Solubility
Reacts with water.

Notes
Air and moisture sensitive. Incompatible with oxidizing agents, water/ moisture.

Specifications

Chemical Identifiers

• CAS: 1019-71-2
• Molecular Formula: C14H14ClP
• Molecular Weight (g/mol): 248.69
• MDL Number: MFCD01630844
• InChI Key: BJBXRRHIBSXGLF-UHFFFAOYSA-N
• Synonym: bis 4-methylphenyl chlorophosphine, chlorodi p-tolyl phosphine, chlorodi-p-tolylphosphine, chlorobis 4-methylphenyl phosphine, bis 4-methylphenyl phosphinous chloride, chlorobis 4-methylphenyl phosphane, chloro-bis 4-methylphenyl phosphane, di-p-tolylchlorophosphine, chloro bis-p-tolyl phosphane, di p-tolyl phosphinous chloride
• PubChem CID: 4188608
• IUPAC Name: chloro-bis(4-methylphenyl)phosphane
• SMILES: CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)Cl

• Density: 1.159
• Boiling Point: 180°C to 184°C (10 mmHg)
• Quantity: 1 g
• UN Number: UN1760
• Sensitivity: Air and moisture sensitive
• Solubility Information: Reacts with water.
• Formula Weight: 248.69
• Percent Purity: 95%
• Chemical Name or Material: Chlorodi(p-tolyl)phosphine

Safety and Handling

Hazard Category	H314-H335
Hazard Statement	GHS H Statement H314-H318 Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statement	P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
DOTInformation	Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUIDS, N.O.S.
EINECSNumber	000-000-0
TSCA	No
Recommended Storage	Ambient temperatures; Store under Nitrogen

SDS

RUO – Research Use Only