Dess-Martin periodinane

Catalog No. AAL1577903

Supplier: Thermo Scientific Chemicals L1577903

Description

CAS: 87413-09-0 | C13H13IO8 | 424.14 g/mol

Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.

Solubility
Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.

Notes
Store in cool place. Air and moisture sensitive. Incompatible with strong reducing agents, combustible material and water.

Specifications

Chemical Identifiers

• CAS: 87413-09-0
• Molecular Formula: C13H13IO8
• Molecular Weight (g/mol): 424.14
• MDL Number: MFCD00130127
• InChI Key: NKLCNNUWBJBICK-UHFFFAOYSA-N
• PubChem CID: 159087
• SMILES: CC(=O)O[I]1(OC(C)=O)(OC(C)=O)OC(=O)C2=CC=CC=C12

• Melting Point: 130°C to 132°C (decomposition)
• Quantity: 1 g
• UN Number: UN1479
• Beilstein: 4548207
• Sensitivity: Air, light, and moisture sensitive
• Merck Index: 14,2933
• Synonym: dess-martin periodinane, triacetoxyperiodinane, 1,1,1-triacetoxy-1,1-dihydro-1,2-benziodoxol-3 1h-one, dess-martin reagent, dess-martinperiodinane, dess-martin, dess martin periodinane, dess martin, dess-martin periodane
• Solubility Information: Soluble in chloroform,acetone,acetonitrile and methylene chloride. Slightly soluble in ether and hexane.
• IUPAC Name: (1,1-diacetyloxy-3-oxo-1$l^{5},2-benziodoxol-1-yl) acetate
• Formula Weight: 424.15
• Percent Purity: ≥95%
• Chemical Name or Material: Dess-Martin periodinane

Safety and Handling

Hazard Category	H272-H315-H319-H335
Hazard Statement	GHS H Statement H272-H315-H319-H335 May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statement	P210-P220-P221-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c
DOTInformation	Transport Hazard Class: 5.1; Packing Group: III; Proper Shipping Name: OXIDIZING SOLID, N.O.S.
TSCA	No
Recommended Storage	Store at -20°C; Store under Argon

SDS

RUO – Research Use Only