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Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II), 98%

Catalog No. AA1393204
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Catalog No. AA1393204 Supplier Thermo Scientific Chemicals Supplier No. 01393204
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Description

CAS: 14647-23-5 | C26H24Cl2NiP2 | 528.02 g/mol

Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II) is a reactant involved in Kumada catalyst-transfer polycondensation, oxidation of carboranyl phosphine ligands, synthesis of nickel-iron dithiolato hydrides, Ullmann reactions - homocoupling reactions, co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers, catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 14647-23-5
Molecular Formula C26H24Cl2NiP2
Molecular Weight (g/mol) 528.02
MDL Number MFCD00013313
InChI Key XXECWTBMGGXMKP-UHFFFAOYSA-L
Synonym 1,2-bis diphenylphosphino ethane nickel ii chloride
PubChem CID 131664338
IUPAC Name nickel(2+) [2-(diphenylphosphaniumyl)ethyl]diphenylphosphanium dichloride
SMILES Cl[Ni]Cl.C(CP(C1=CC=CC=C1)C1=CC=CC=C1)P(C1=CC=CC=C1)C1=CC=CC=C1

Specifications

Melting Point 263°C to 265°C
Color Brown to Orange-Red
Quantity 2 g
Solubility Information Insoluble in water.
Formula Weight 528.02
Percent Purity 98%
Physical Form Powder
Chemical Name or Material Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II)

Safety and Handling

Hazard Category H315-H319-H335-H351
Hazard Statement GHS H Statement
H351-H302-H312-H332-H315-H319-H317-H335
Suspected of causing cancer.
Harmful if swallowed.
Harmful in contact with skin.
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
May cause respiratory irritation.
Precautionary Statement P201-P202-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P308+P313-P312-P332+P313-P362-P501c
TSCA No
Recommended Storage Ambient temperatures
SDS

RUO – Research Use Only

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