Diethyl diallylmalonate, 97+%

Catalog No.	Quantity
AAA1246030	250 g
AAA1246009	10 g
AAA1246018	50 g

Catalog No. AAA1246030 Supplier Thermo Scientific Chemicals Supplier No. A1246030

Description

CAS: 3195-24-2 | C13H20O4 | 240.299 g/mol

Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke?s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke′s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.

Solubility
Sparingly Soluble in water. (0.72 g/L) (25°C)

Notes
Store under cool dry place. Ensure good ventilation.

Specifications

Chemical Identifiers

• CAS: 3195-24-2
• Molecular Formula: C13H20O4
• Molecular Weight (g/mol): 240.299
• MDL Number: MFCD00009126
• InChI Key: LYUUVYQGUMRKOV-UHFFFAOYSA-N
• PubChem CID: 76664
• IUPAC Name: diethyl 2,2-bis(prop-2-enyl)propanedioate
• SMILES: CCOC(=O)C(CC=C)(CC=C)C(=O)OCC

• Density: 0.993
• Boiling Point: 242°C to 244°C
• Flash Point: >110°C (230°F)
• Refractive Index: 1.446
• Quantity: 250 g
• Beilstein: 1790529
• Synonym: diethyl diallylmalonate, diethyl 2,2-diallylmalonate, diallylmalonic acid diethyl ester, propanedioic acid, di-2-propenyl-, diethyl ester, 1,3-diethyl 2,2-bis prop-2-en-1-yl propanedioate, diethyl 2,2-diprop-2-enylpropane-1,3-dioate, diethyldiallylmalonate, malonic acid, diallyl-, diethyl ester, diethyl2,2-diallylmalonate, acmc-1cp69
• Solubility Information: Sparingly Soluble in water. (0.72g/L) (25°C)
• Formula Weight: 240.3
• Percent Purity: 98%
• Chemical Name or Material: Diethyl diallylmalonate

Safety and Handling

Hazard Category	H315-H319-H335
Hazard Statement	GHS H Statement H315-H319-H335 Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statement	P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
EINECSNumber	221-696-4
TSCA	No
Recommended Storage	Ambient temperatures

SDS

RUO – Research Use Only