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Magnesium bromide diethyl etherate, 98%

Catalog No. AAL1548114
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Quantity:
25 g

CAS: 29858-07-9 | C4H10Br2MgO | 258.24 g/mol

The magnesium bromide diethyl etherate (MgBr2· OEt2)-methyl sulfide (Me2S) system is useful for the mild and chemo-selective deprotection of p-methoxybenzyl (PMB) ether. Lewis acid for catalysis of Diels-Alder reactions of homochiral 2-sulfinylmaleates with cyclopentadiene. Magnesium bromide diethyl etherate is used in the synthesis of silicon-containing azole derivatives.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
The magnesium bromide diethyl etherate (MgBr2· OEt2)-methyl sulfide (Me2S) system is useful for the mild and chemo-selective deprotection of p-methoxybenzyl (PMB) ether. Lewis acid for catalysis of Diels-Alder reactions of homochiral 2-sulfinylmaleates with cyclopentadiene. Magnesium bromide diethyl etherate is used in the synthesis of silicon-containing azole derivatives.

Solubility
Hydrolyzes in water.

Notes
Moisture sensitive.Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, moisture.
TRUSTED_SUSTAINABILITY

Specifications

CAS 29858-07-9
Flash Point 35°C (95°F)
Molecular Formula C4H10Br2MgO
Linear Formula (CH3CH2)2O·MgBr2
Quantity 25 g
MDL Number MFCD00064500
UN Number UN1325
Sensitivity Moisture sensitive
Synonym magnesium bromide diethyl etherate, magnesium bromide etherate, magnesium bromide ethyl etherate, grignard reagent
Solubility Information Hydrolyzes in water.
InChI Key JGZKUKYUQJUUNE-UHFFFAOYSA-L
SMILES Br[Mg]Br.CCOCC
IUPAC Name magnesium;ethoxyethane;dibromide
Molecular Weight (g/mol) 258.24
PubChem CID 11010650
Formula Weight 258.24
Percent Purity 98%
Chemical Name or Material Magnesium bromide diethyl etherate
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Hazard Category H228-H500
Hazard Statement GHS H Statement
H228
Flammable solid.
Precautionary Statement P210-P240-P241-P280-P370+P378q
DOTInformation Transport Hazard Class: 4.1; Packing Group: II; Proper Shipping Name: FLAMMABLE SOLIDS, ORGANIC, N.O.S.
TSCA No
Recommended Storage Ambient temperatures

RUO – Research Use Only

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