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  7. tert-Butyldimethylsilyl trifluoromethanesulfonate, 98%, Thermo Scientific™

tert-Butyldimethylsilyl trifluoromethanesulfonate, 98%, Thermo Scientific™

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Quantity:
5g
25g
69739-34-0
C7H15F3O3SSi
264.33
MFCD00000405
WLLIXJBWWFGEHT-UHFFFAOYSA-N
tert-butyldimethylsilyl trifluoromethanesulfonate, trifluoromethanesulfonic acid tert-butyldimethylsilyl ester, tbdms triflate, t-butyldimethylsilyl triflate, tert-butyldimethylsilyl trifluoromethanesulphonate, tbdms-otf, tert-butyldimethylsilyl triflate, silane tbm2 triflate, t-butyldimethylsilyltrifluoromethanesulfonate, t-butylmethylsilyl triflate
123564
[tert-butyl(dimethyl)silyl] trifluoromethanesulfonate
CC(C)(C)[Si](C)(C)OS(=O)(=O)C(F)(F)F
69739-34-0
C7H15F3O3SSi
264.33
MFCD00000405
WLLIXJBWWFGEHT-UHFFFAOYSA-N
tert-butyldimethylsilyl trifluoromethanesulfonate, trifluoromethanesulfonic acid tert-butyldimethylsilyl ester, tbdms triflate, t-butyldimethylsilyl triflate, tert-butyldimethylsilyl trifluoromethanesulphonate, tbdms-otf, tert-butyldimethylsilyl triflate, silane tbm2 triflate, t-butyldimethylsilyltrifluoromethanesulfonate, t-butylmethylsilyl triflate
123564
[tert-butyl(dimethyl)silyl] trifluoromethanesulfonate
CC(C)(C)[Si](C)(C)OS(=O)(=O)C(F)(F)F

Description

This Thermo Scientific brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific.

Applications
tert-Butyldimethylsilyl trifluoromethanesulfonate is involved in the introduction of a bulky tert-butyl dimethylsilyl group onto a cis-bis(alkenyl)oxirane used in Cope rearrangement. It is associated with a thiolane and promotes the chalcogenide-Morita-Baylis-Hillman reaction. Further, it is used as a highly reactive silylating agent. In addition to this, it is used to prepare enol silyl ethers by reacting with ketones and lactones.

Solubility
Slightly miscible with chloroform.

Notes
Moisture sensitive. Store in a cool place. Incompatible with strong acids.
Density 1.151
Boiling Point 65°C to 67°C (12mmHg)
Flash Point 36°C (96°F)
UN Number UN2920
Beilstein 2370068
Refractive Index 1.386
Quantity 25g
Solubility Information Slightly miscible with chloroform.
Sensitivity Moisture sensitive
Formula Weight 264.34
Percent Purity 98%
Chemical Name or Material tert-Butyldimethylsilyl trifluoromethanesulfonate
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Safety and Handling

GHS H Statement
H314-H318-H226
Causes severe skin burns and eye damage.
Causes serious eye damage.
Flammable liquid and vapor.

P210-P233-P240-P241-P242-P243-P260-P264b-P270-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

H226-H302-H314

DOTInformation : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUIDS, FLAMMABLE, N.O.S.

EINECSNumber : 274-102-0

TSCA : No

Recommended Storage : Store at -20°C; Store under Nitrogen

SDS

RUO – Research Use Only