Methylene Chloride
What Is Methylene Chloride?
Methylene chloride, also called dichloromethane (DCM), is a volatile, polar, organochloride compound that’s miscible with many organic solvents.
A colorless liquid at room temperature, methylene chloride has a sweet, penetrating odor. It’s a member of the halomethanes or chloromethanes group where one or more hydrogens has been replaced by a halogen (chlorine).
Though non-combustible and non-flammable, methylene chloride can emit toxic chloride fumes when exposed to high temperatures. The vapors are narcotic in high concentrations.
Dichloromethane is formally rated as a probable carcinogen by IARC 2A and is a potentially toxic compound. It has been detected in feces, saliva, and other biofluids.
Synonyms: Dichloromethane, methylene dichloride, methylene bichloride, DCM

Physical and Chemical Properties
Property | Value | ||
---|---|---|---|
Molecular Weight | 84.93 g/mol | ||
Density | 1.3255 g/mL at 20ºC | ||
Boiling Point | 40ºC | ||
Melting Point | -95.1oC | ||
Flash Point | 5.5oC | ||
Viscosity | 0.413 cP at 25ºC | ||
Dielectric Constant | 8.93 at 25oC | ||
Dipole Moment | 1.6 | ||
UV Cutoff | 233 nm | ||
Refractive Index | 1.4244 at 20oC | ||
Vapor Pressure | 435 mm Hg at 25oC | ||
Water Solubility | 13 mg/mL at 25°C | ||
Heat of Combustion | 28.82 x 106 J/kg at 25oC | ||
Surface Tension | 28.2 dyne/cm at 20oC |
Uses
Methylene chloride is commonly used as a solvent for organic reactions and extractions, and in drug and pesticide manufacturing. It’s also used as a refrigerant and paint stripper and to remove caffeine from coffee and tea.
Designations and Grades
Property | Value | ||
---|---|---|---|
CAS Number | 75-09-2 | ||
MDL Number | MFCD00000881 | ||
RIDAD/UN Number | 1593 | ||
Beilstein Registry | 1730800 | ||
EG/EC Number | 200-838-9 | ||
NSC Number | 406122 | ||
ICSC Number | 0058 | ||
RTECS Number | PA8050000 |
Grades
ACS/ACS Reagent/Certified ACS
Anhydrous/Dry/Extra Dry/Low Water
Biochemical
Environmental
FCC
GC/Capillary GC
GC/Pesticide Residue
GC-MS
HPLC
Laboratory/Technical
NF
Pesticide
Spectrophotometry