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Alfa Aesar™ 4,4'-Di-tert-butylbiphenyl, 99%
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Quantity:
5g
25g
100g
Description
Applications
It is used in the generation of 1,2-di(lithiomethyl)benzene. It is found to accept electrons from Li metal to give a radical anion which is highly effective in the conversion of alkyl halides to alkyllithiums. 4,4′-Di-tert-butylbiphenyl is used in production of homoallylic amine derivatives. It is also used in the preparation of lithium di-tert-butylbiphenylide, a radical anion, superior to sodium or lithium naphthalenides for metalation reactions. Along with lithium, 4,4′-Di-tert-butylbiphenyl catalyzes; reaction of chloromethyl ethyl ether and different carbonyl compounds to yield corresponding hydroxyethers and reductive opening of N-phenylazetidine.
Solubility
Solubility in toluene; almost transparency. Soluble in dioxane: 0.1 g/mL, (clear).
Notes
Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
It is used in the generation of 1,2-di(lithiomethyl)benzene. It is found to accept electrons from Li metal to give a radical anion which is highly effective in the conversion of alkyl halides to alkyllithiums. 4,4′-Di-tert-butylbiphenyl is used in production of homoallylic amine derivatives. It is also used in the preparation of lithium di-tert-butylbiphenylide, a radical anion, superior to sodium or lithium naphthalenides for metalation reactions. Along with lithium, 4,4′-Di-tert-butylbiphenyl catalyzes; reaction of chloromethyl ethyl ether and different carbonyl compounds to yield corresponding hydroxyethers and reductive opening of N-phenylazetidine.
Solubility
Solubility in toluene; almost transparency. Soluble in dioxane: 0.1 g/mL, (clear).
Notes
Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
Specifications
Boiling Point | 190°C to 192°C (13mmHg) |
Quantity | 25g |
Melting Point | 126°C to 129°C |
Beilstein | 2095855 |
Formula Weight | 266.43 |
Percent Purity | 99% |
Chemical Name or Material | 4,4'-Di-tert-butylbiphenyl |
Safety and Handling
EINECSNumber : 216-615-4
TSCA : No
Recommended Storage : Ambient temperatures