4-Chlorophenylmagnesium bromide, 1M solution in THF/toluene, AcroSeal™

Catalog No.	Quantity	Packaging
AC377251000	100 mL	AcroSeal™ Glass bottle
AC377258000	800 mL	AcroSeal™ Glass bottle

Catalog No. AC377251000 Supplier Thermo Scientific Chemicals Supplier No. 377251000

Description

CAS: 873-77-8 | C6H4BrClMg | 215.76 g/mol

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

• CAS: 873-77-8 , 109-99-9 , 108-88-3
• Molecular Formula: C6H4BrClMg
• Molecular Weight (g/mol): 215.76
• MDL Number: MFCD00009926
• InChI Key: CDEMHJCJMMOFMB-UHFFFAOYSA-M
• Synonym: 4-chlorophenylmagnesium bromide, bromo p-chlorophenyl magnesium, bromo 4-chlorophenyl magnesium, p-chlorophenylmagnesium bromide, 4-chlorophenyl magnesium bromide, pubchem24069, 4-chlorophenylmagnesiumbromide, 4-chlorphenylmagnesium bromide, 4-chloro phenylmagnesiumbromide, 4-chlorophenyhnagnesium bromide, grignard reagent
• PubChem CID: 101888
• SMILES: ClC1=CC=C([Mg]Br)C=C1

• Color: Yellowish-green solution
• CAS Min %: 21.58, 76.27
• CAS Max %: 23.73, 78.42
• Linear Formula: Cl(C₆H₆)MgBr
• Concentration: 1M, exact strength on the certificate of analysis
• Density: 1.0000g/mL
• Solubility Information: Solubility in water: vigorous reaction.
• IUPAC Name: bromo(4-chlorophenyl)magnesium
• Formula Weight: 215.76
• Packaging: AcroSeal™ Glass bottle
• Specific Gravity: 1
• Quantity: 100 mL
• Flash Point: −21°C
• Chemical Name or Material: 4-Chlorophenylmagnesium bromide

Safety and Handling

Hazard Category	Danger
Hazard Statement	GHS H Statement May cause damage to organs through prolonged or repeated exposure. Causes severe skin burns and eye damage. May cause drowsiness or dizziness. May be fatal if swallowed and enters airways. Suspected of damaging the unborn child. In contact with water releases flammable gases which may ignite spontaneously. Highly flammable liquid and vapor. Suspected of causing cancer. Reacts violently with water. May form explosive peroxides. May cause respiratory irritation.
Precautionary Statement	GHS P Statement Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Handle under inert gas. Protect from moisture. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

SDS

RUO – Research Use Only