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Bismuth(III) chloride, 97+% (dry wt.), may cont. up to 3% water, Thermo Scientific Chemicals

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Quantity:
25 g
100 g
500 g
7787-60-2
BiCl3
315.33
MFCD00003461
JHXKRIRFYBPWGE-UHFFFAOYSA-K
bismuth trichloride, bismuth chloride, trichlorobismuthine, trichlorobismuth, bismuth iii chloride, bismuthine, trichloro, trichlorobismute, bismuth lll chloride
24591
trichlorobismuthane
Cl[Bi](Cl)Cl
7787-60-2
BiCl3
315.33
MFCD00003461
JHXKRIRFYBPWGE-UHFFFAOYSA-K
bismuth trichloride, bismuth chloride, trichlorobismuthine, trichlorobismuth, bismuth iii chloride, bismuthine, trichloro, trichlorobismute, bismuth lll chloride
24591
trichlorobismuthane
Cl[Bi](Cl)Cl

Bismuth(III) chloride is used as a catalyst in organic synthesis and to prepare other bismuth salts. It is used as a starting material for the preparation of bismuthoxychloride upon hydrolysis. It is an oxidizing agent to prepare metallic bismuth by reducing agent. Further, it catalyzes the Michael reaction and the Mukaiyama-aldol reaction. In addition to this, it is a Lewis acid.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Bismuth(III) chloride is used as a catalyst in organic synthesis and to prepare other bismuth salts. It is used as a starting material for the preparation of bismuthoxychloride upon hydrolysis. It is an oxidizing agent to prepare metallic bismuth by reducing agent. Further, it catalyzes the Michael reaction and the Mukaiyama-aldol reaction. In addition to this, it is a Lewis acid.

Solubility
Soluble in hydrochloric acid, nitric acid, diethyl ether, ethyl acetate and acetone. Insoluble in alcohol.

Notes
Hygroscopic. Incompatible with strong oxidizing agents.
Boiling Point ∼430°C (sublimation)
Melting Point 230°C to 232°C
Quantity 100 g
UN Number UN3260
Merck Index 14,1262
Solubility Information Soluble in hydrochloric acid,nitric acid,diethyl ether,ethyl acetate and acetone. Insoluble in alcohol.
Formula Weight 315.34
Percent Purity 98%
Concentration or Composition (by Analyte or Components) May contain up to 3% water
Odor Irritating
Sensitivity Moisture sensitive
Density 4.75
Assay (dry wt.)
Chemical Name or Material Bismuth (III) chloride
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GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

H315-H319-H335

DOTInformation : Transport Hazard Class: 8; Packing Group: III; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.

EINECSNumber : 232-123-2

RTECSNumber : EB2690000

TSCA : Yes

Recommended Storage : Ambient temperatures

RUO – Research Use Only