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  6. Di-^m-bromobis(tri-tert-butylphosphine)dipalladium(I), Thermo Scientific Chemicals

Di-^m-bromobis(tri-tert-butylphosphine)dipalladium(I), Thermo Scientific Chemicals

Catalog Number AA4444602
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Quantity:
0.1 g
0.5 g
2 g
185812-86-6
C12H27BrPPd-
388.646
MFCD04114019
WIADNXKBAGKNOT-UHFFFAOYSA-M
palladium i tri-tert-butylphosphine bromide, acmc-1c5o0, qmkdjymohbicon-uhfffaoysa-m, palladium i tri-tertbutylphosphine bromide
71317307
palladium;tritert-butylphosphane;bromide
CC(C)(C)P(C(C)(C)C)C(C)(C)C.[Br-].[Pd]
185812-86-6
C12H27BrPPd-
388.646
MFCD04114019
WIADNXKBAGKNOT-UHFFFAOYSA-M
palladium i tri-tert-butylphosphine bromide, acmc-1c5o0, qmkdjymohbicon-uhfffaoysa-m, palladium i tri-tertbutylphosphine bromide
71317307
palladium;tritert-butylphosphane;bromide
CC(C)(C)P(C(C)(C)C)C(C)(C)C.[Br-].[Pd]

Description

Coupling reactions. Will activate aryl chloride and sterically hindered or electron rich aryl/vinyl bromides and iodides. Especially active in difficult aminations.Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I) is used as a catalyst for Suzuki coupling, Negishi coupling and Buchwald-hartwig amination reactions. It is used as a catalyst for C-C, C-N and C-S bond formation, gamma-arylation of alfa,beta-unsaturated esters and diastereoselective arylation of 4-substituted cyclohexyl esters. It is also involved in aromatic halide substitution reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

  • Coupling reactions
  • Will activate aryl chloride and sterically hindered or electron rich aryl/vinyl bromides and iodides
  • Especially active in difficult aminations
TRUSTED_SUSTAINABILITY
Color Green
Linear Formula [Pd(C4H9)3PBr]2
Quantity 0.5 g
Sensitivity Air sensitive
Solubility Information Soluble in benzene and tolueneSoluble in tetrahydrofuran,toluene,dichloromethane and chloroform; Insoluble in alcohols and water.
Formula Weight 777.29
Physical Form Powder
Chemical Name or Material Di-mu-bromobis (tri-tert-butylphosphine)dipalladium (I)

Safety and Handling

Hazard Category H315-H319-H335
Hazard Statement GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary Statement P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
TSCA No
Recommended Storage Store at -20°C; Store under Argon
SDS

RUO – Research Use Only

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