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  7. Dibenzyl carbonate, 98%, Thermo Scientific Chemicals

Dibenzyl carbonate, 98%, Thermo Scientific Chemicals

Catalog Number AAA1146418
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Quantity:
10 g
50 g
250 g
3459-92-5
C15H14O3
242.27
MFCD00014436
PIZLBWGMERQCOC-UHFFFAOYSA-N
carbonic acid, bis phenylmethyl ester, benzyl carbonate, carbonic acid, dibenzyl ester, dibenzylcarbonate, carbonic acid dibenzyl ester, phenylmethyl phenylmethoxy formate, dibenzyl carbonate, acmc-209i8r, carbonic acid,bis phenylmethyl ester
77002
dibenzyl carbonate
O=C(OCC1=CC=CC=C1)OCC1=CC=CC=C1
3459-92-5
C15H14O3
242.27
MFCD00014436
PIZLBWGMERQCOC-UHFFFAOYSA-N
carbonic acid, bis phenylmethyl ester, benzyl carbonate, carbonic acid, dibenzyl ester, dibenzylcarbonate, carbonic acid dibenzyl ester, phenylmethyl phenylmethoxy formate, dibenzyl carbonate, acmc-209i8r, carbonic acid,bis phenylmethyl ester
77002
dibenzyl carbonate
O=C(OCC1=CC=CC=C1)OCC1=CC=CC=C1

Description

Ionic liquids can effectively accelerate slow N-benzylation reactions utilizing dibenzyl carbonate as an alkylating reagent. Dibenzyl carbonate (DBzlC) has been used to benzylate phenylacetonitrile, benzyl phenylacetate and phenol. Selective N, N-dibenzylation of primary aliphatic amines was carried with dibenzyl carbonate in the presence of phosphonium salts.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Ionic liquids can effectively accelerate slow N-benzylation reactions utilizing dibenzyl carbonate as an alkylating reagent. Dibenzyl carbonate (DBzlC) has been used to benzylate phenylacetonitrile, benzyl phenylacetate and phenol. Selective N, N-dibenzylation of primary aliphatic amines was carried with dibenzyl carbonate in the presence of phosphonium salts.

Solubility
Sparingly Soluble (0.099 g/L) (25°C).

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, heat.
TRUSTED_SUSTAINABILITY
Melting Point 27°C to 30°C
Boiling Point 150°C to 155°C (0.8 mmHg)
Flash Point >110°C (230°F)
Refractive Index 1.5485
Quantity 50 g
Beilstein 1882864
Sensitivity Air sensitive
Solubility Information Sparingly Soluble (0.099g/L) (25°C).
Formula Weight 242.27
Percent Purity 98%
Chemical Name or Material Dibenzyl carbonate
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Safety and Handling

Hazard Category H302+H312
Precautionary Statement P264b-P270-P280-P301+P312-P302+P352-P312-P330-P363-P501c
EINECSNumber 222-401-1
TSCA Yes
Recommended Storage Keep cold; Store under Argon
SDS

RUO – Research Use Only

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