Glycidyl (S)-(+)-3-nitrobenzenesulfonate, 98%

Description

CAS: 115314-14-2 | C9H9NO6S | 259.23 g/mol

Glycidyl (S)-(+)-3-nitrobenzenesulfonate is used in the synthesis of enantiopure bisoprolol by reacting with phenols using cesium fluoride as catalyst. It is also involved in the preparation of orally active HIV-1 protease inhibitor.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Glycidyl (S)-(+)-3-nitrobenzenesulfonate is used in the synthesis of enantiopure bisoprolol by reacting with phenols using cesium fluoride as catalyst. It is also involved in the preparation of orally active HIV-1 protease inhibitor.

Solubility
Soluble in chloroform, methylene chloride and tetrahydrofuran. Insoluble in hexane.

Notes
Moisture sensitive. Store in a cool place. Incompatible with strong oxidizing agents and strong bases.

Specifications

Chemical Identifiers

• CAS: 115314-14-2
• Molecular Formula: C9H9NO6S
• Molecular Weight (g/mol): 259.23
• MDL Number: MFCD00064582
• InChI Key: AIHIHVZYAAMDPM-QMMMGPOBSA-N
• Synonym: s-+-glycidyl nosylate, s-glycidyl nosylate, s-glycidyl 3-nitrobenzenesulfonate, s-oxiran-2-ylmethyl 3-nitrobenzenesulfonate, s-+-glycidyl 3-nitrobenzenesulfonate, glycidyl 3-nitrobenzenesulfonate, ccris 6394, 2s-+-glycidyl-3-nitrobenzenesulfonate, oxiranylmethyl s-3-nitrobenzenesulfonate, 2s-oxiran-2-yl methyl 3-nitrobenzenesulfonate
• PubChem CID: 146490
• IUPAC Name: [(2S)-oxiran-2-yl]methyl 3-nitrobenzenesulfonate
• SMILES: [O-][N+](=O)C1=CC=CC(=C1)S(=O)(=O)OC[C@@H]1CO1

• Melting Point: 63°C to 66°C
• Quantity: 25 g
• Beilstein: 4704457
• Sensitivity: Moisture sensitive
• Solubility Information: Soluble in chloroform,methylene chloride and tetrahydrofuran. Insoluble in hexane.
• Formula Weight: 259.23
• Percent Purity: 98%
• Chemical Name or Material: Glycidyl (S)-(+)-3-nitrobenzenesulfonate

Safety and Handling

Hazard Category	H315-H319-H335
Hazard Statement	GHS H Statement H315-H319-H335 Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statement	P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
RTECSNumber	DB7192010
TSCA	No
Recommended Storage	Ambient temperatures; Store under Nitrogen

SDS

RUO – Research Use Only