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Lanthanum(III) isopropoxide, La 40%

Catalog No. AA1461602
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Catalog No. AA1461602 Supplier Thermo Scientific Chemicals Supplier No. 01461602
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Description

CAS: 19446-52-7 | C9H21LaO3 | 316.169 g/mol

Lanthanum(III) isopropoxide finds application in asymmetric catalysis. It forms complex with an (S,S)-phenyl-linked-binaphthol ,which enhances a catalytic 1,4-addition of malonate to cyclic and acyclic enones. It acts as a co-catalyst with copper fluoride-triphenylphosphine in catalytic allylation of ketoimines.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 19446-52-7
Molecular Formula C9H21LaO3
Molecular Weight (g/mol) 316.169
MDL Number MFCD00015305
InChI Key SORGMJIXNUWMMR-UHFFFAOYSA-N
Synonym lanthanum isopropoxide, lanthanum iii isopropoxide, acmc-20ako6, lanthanum triisopropoxide, lanthanum 3+ ion tris propan-2-olate, lanthanum 3+ tris propan-2-olate
PubChem CID 9858075
IUPAC Name lanthanum(3+);propan-2-olate
SMILES CC(C)[O-].CC(C)[O-].CC(C)[O-].[La+3]

Specifications

Melting Point 120°C to 128°C
Color White
Boiling Point 170°C (0.04 mmHg)(sublimation)
Odor Alcohol-like
Linear Formula La[OCH(CH3)2]3
Quantity 0.5 g
UN Number UN2925
Sensitivity Air and moisture sensitive
Solubility Information Soluble in terahydrofuran,toluene,hexane and isopropyl alcohol.
Formula Weight 316.18
Concentration or Composition (by Analyte or Components) La 40%
Physical Form Powder
Chemical Name or Material Lanthanum(III) isopropoxide
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Safety and Handling

Hazard Category H228-H261-H314-H335
Hazard Statement GHS H Statement
H314-H318-H228
Causes severe skin burns and eye damage.
Causes serious eye damage.
Flammable solid.
Precautionary Statement P210-P223-P231+P232-P240-P241-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P335+P334-P363-P370+P378q-P501c
DOTInformation Hazard Class: 4.1; Packaging Group: II
TSCA No
Recommended Storage Ambient temperatures
SDS

RUO – Research Use Only

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