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Alfa Aesar™ Methyl dichloroacetate, 99%
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Quantity:
100g
500g
Description
Applications
Methyl dichloroacetate may be used in the diastereoselctive synthesis of bicyclic chlorocyclopropane, as difunctional initiator during atom transfer radical polymerization of methyl or n-butyl acrylate, as reagent during CrCl2-induced olefination of aldehydes. It is a reactant involved in nucleophilic substitution reactions with nitro(pentafluorosulfanyl)benzenes, azide-alkyl halide cycloaddition and atom transfer radical addition, Chemical modification of STn antigen for enhancement of synthetic carbohydrate vaccines, three component reaction of arynes with cyclic ethers and active methines, catalytic radical haloalkylation for synthesis of neodysidenin and addition reactions for syntehsis of enantiopure 3,4-diamino esters or amides.
Solubility
Soluble in water. (4 g/L).
Notes
Store at room temperature. Incompatible with oxidizing agents. Ensure proper ventilation.
Methyl dichloroacetate may be used in the diastereoselctive synthesis of bicyclic chlorocyclopropane, as difunctional initiator during atom transfer radical polymerization of methyl or n-butyl acrylate, as reagent during CrCl2-induced olefination of aldehydes. It is a reactant involved in nucleophilic substitution reactions with nitro(pentafluorosulfanyl)benzenes, azide-alkyl halide cycloaddition and atom transfer radical addition, Chemical modification of STn antigen for enhancement of synthetic carbohydrate vaccines, three component reaction of arynes with cyclic ethers and active methines, catalytic radical haloalkylation for synthesis of neodysidenin and addition reactions for syntehsis of enantiopure 3,4-diamino esters or amides.
Solubility
Soluble in water. (4 g/L).
Notes
Store at room temperature. Incompatible with oxidizing agents. Ensure proper ventilation.
Specifications
| Refractive Index | 1.442 |
| Density | 1.38 |
| Boiling Point | 142°C to 144°C |
| Quantity | 100g |
| Melting Point | -52°C |
| Flash Point | 70°C (158°F) |
| Odor | Pungent |
| Linear Formula | Cl2CHCO2CH3 |
| UN Number | UN2299 |
| Solubility Information | Soluble in water. (4g/L). |
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Safety and Handling
GHS H Statement
H331-H227-H315-H319-H335
Toxic if inhaled.
Combustible liquid.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c
H227-H315-H319-H335
DOTInformation : Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: METHYL DICHLOROACETATE
EINECSNumber : 204-146-8
RTECSNumber : AG6625000
TSCA : Yes
Recommended Storage : Ambient temperatures