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  8. Methyl hydrogen malonate, 96%, Thermo Scientific Chemicals

Methyl hydrogen malonate, 96%, Thermo Scientific Chemicals

Catalog Number AAH2777214
Click to view available options
Quantity:
5 g
25 g
100 g
16695-14-0
C4H6O4
118.088
MFCD00667796
PBVZQAXFSQKDKK-UHFFFAOYSA-N
methyl hydrogen malonate, malonic acid monomethyl ester, 3-methoxy-3-oxo-propanoic acid, 1-methyl malonate, hydrogen methyl malonate
538366
3-methoxy-3-oxopropanoic acid
COC(=O)CC(=O)O
16695-14-0
C4H6O4
118.088
MFCD00667796
PBVZQAXFSQKDKK-UHFFFAOYSA-N
methyl hydrogen malonate, malonic acid monomethyl ester, 3-methoxy-3-oxo-propanoic acid, 1-methyl malonate, hydrogen methyl malonate
538366
3-methoxy-3-oxopropanoic acid
COC(=O)CC(=O)O

Description

Lactonization of olefins with monomethyl ester of malonic acid and ceric ammonium nitrate was carried out in acetic acid and in acetonitrile under simple mechanical stirring or ultrasound irradiation. Lactonization of olefins with CAN and monomethyl ester of malonic acid under ultrasound irradiation shows an acceleration with respect to the analogous mechanically stirred reaction.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Lactonization of olefins with monomethyl ester of malonic acid and ceric ammonium nitrate was carried out in acetic acid and in acetonitrile under simple mechanical stirring or ultrasound irradiation. Lactonization of olefins with CAN and monomethyl ester of malonic acid under ultrasound irradiation shows an acceleration with respect to the analogous mechanically stirred reaction.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
TRUSTED_SUSTAINABILITY
Density 1.128
Refractive Index 1.4295
Quantity 25 g
Formula Weight 118.09
Percent Purity 96%
Chemical Name or Material Methyl hydrogen malonate

Safety and Handling

Hazard Category H315-H319-H335
Hazard Statement GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary Statement P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
TSCA No
Recommended Storage Keep cold
SDS

RUO – Research Use Only

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