Alfa Aesar Phenylselenenyl bromide, 98%
Manufacturer: Alfa Aesar A1190603
Employed in the synthesis of enones by selenenylation of α-cyano ketones with lithium naphthalenide. Phenylselenyl bromide was used in the preparation of exo-2-methyl-7-phenylselenyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione and endo-2-methyl-7-phenylselanyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione.
Soluble in toluene, very faint turbidity.
Moisture Sensitive. Store away from air and water/moisture. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.
|107° to 108°C (15mmHg)|
|56° to 62°C|
Safety and Handling
SDS & Safety Documents
GHS H Statement
Toxic if swallowed.
Toxic if inhaled.
May cause damage to organs through prolonged or repeated exposure.
GHS P Statement
Do not breathe dust/fume/gas/mist/vapors/spray.
Avoid breathing dust/fume/gas/mist/vapors/spray.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
DOTInformation : Transport Hazard Class: 6.1; Packing Group: II; Proper Shipping Name: TOXIC SOLIDS, CORROSIVE, ORGANIC, N.O.S.