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  7. (Iodomethyl)trimethylsilane, 99%

(Iodomethyl)trimethylsilane, 99%

Catalog No. p-7022375
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AAA1512009 10 g
AAA1512018 50 g
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Catalog No. AAA1512009 Supplier Thermo Scientific Chemicals Supplier No. A1512009
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Description

CAS: 4206-67-1 | C4H11ISi | 214.121 g/mol

(Iodomethyl)trimethylsilane is used for the N-alkylation of amides, in a reaction sequence to prepare unstabilized ylides for [2+3]-cycloadditions. It can react with acetoacetic acid ethyl ester to get 3-trimethylsilanyl-proπonic acid ethyl ester.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(Iodomethyl)trimethylsilane is used for the N-alkylation of amides, in a reaction sequence to prepare unstabilized ylides for [2+3]-cycloadditions. It can react with acetoacetic acid ethyl ester to get 3-trimethylsilanyl-proπonic acid ethyl ester.

Solubility
Difficult to mix.

Notes
Light Sensitive. Store in cool, dry conditions in well sealed containers. Keep container tightly closed.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 4206-67-1
Molecular Formula C4H11ISi
Molecular Weight (g/mol) 214.121
MDL Number MFCD00001077
InChI Key VZNYXGQMDSRJAL-UHFFFAOYSA-N
Synonym iodomethyl trimethylsilane, iodomethyl-trimethylsilane, iodomethyl trimethyl silane, trimethylsilyl methyl iodide, sila-neopentyliodide, trimethylsilylmethyl iodide, acmc-209jn7, trimethyl iodomethyl silane, iodanylmethyl trimethyl silane
PubChem CID 77877
IUPAC Name iodomethyl(trimethyl)silane
SMILES C[Si](C)(C)CI

Specifications

Boiling Point 140°C to 142°C
Quantity 10 g
Linear Formula (CH3)3SiCH2I
UN Number UN1993
Beilstein 1731485
Flash Point 31°C (88°F)
Solubility Information Difficult to mix.
Formula Weight 214.12
Percent Purity 99%
Odor Recognizable
Refractive Index 1.4915
Sensitivity Light sensitive
Density 1.443
Chemical Name or Material (Iodomethyl)trimethylsilane
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Safety and Handling

Hazard Category H226-H315-H319-H335
Hazard Statement GHS H Statement
H226-H315-H319-H335
Flammable liquid and vapour.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary Statement P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c
DOTInformation Transport Hazard Class: 3; Packing Group: III; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
EINECSNumber 224-123-6
TSCA No
Recommended Storage Ambient temperatures
SDS

RUO – Research Use Only

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