Lithium diisopropylamide, 2M sol. in THF/n-heptane/ethylbenzene, AcroSeal™

Description

CAS: 4111-54-0 | C6H14LiN | 107.125 g/mol

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

• CAS: 4111-54-0, 142-82-5, 109-99-9, 100-41-4, 108-18-9
• Molecular Formula: C6H14LiN
• Molecular Weight (g/mol): 107.125
• MDL Number: MFCD00064449
• InChI Key: ZCSHNCUQKCANBX-UHFFFAOYSA-N
• Synonym: lithium diisopropylamide, unii-ol028kiw1i, lithium di-isopropylamide, lithium diisopropyl amide, 2-propanamine, n-1-methylethyl-, lithium salt, ol028kiw1i, lithium di propan-2-yl azanide, 2-propanamine, n-1-methylethyl-, lithium salt 1:1, lithium n,n-diisopropylamide, ipr2nli
• PubChem CID: 2724682
• IUPAC Name: lithium;di(propan-2-yl)azanide
• SMILES: [Li+].CC(C)[N-]C(C)C

• Color: Brown-Red or Orange to Yellow
• Boiling Point: 60.0°C to 136.0°C
• Composition: Solvent: THF 59%, n-Heptane: 28%, Ethylbenzene: 13%
• Concentration: Lithium diisopropylamide: 26.0% (2.0M)
• Fieser: 02,49; 03,184; 04,298; 05,400; 06,334; 07,204; 08,292; 09,280; 10,241; 11,296; 12,277; 14,193; 15,188; 16,15; 17,165
• Merck Index: 15, 3215
• Density: 0.8100g/mL
• Solubility Information: Solubility in water: decomposes. Other solubilities: soluble in thf, n-heptane, ethylbenzene, miscible with liquid aliphatic and aromatic, hydrocarbons, ethers and tertiary amines
• Formula Weight: 107.12
• Percent Purity: 24.6 to 30.0% (Lithium diisopropylamide)
• Packaging: AcroSeal™ Glass bottle
• Specific Gravity: 0.81
• Quantity: 100 mL
• Flash Point: 2°C
• Physical Form: Solution
• Chemical Name or Material: Lithium diisopropylamide, 2M Solution in THF/n-Heptane

Safety and Handling

Hazard Category	Danger
Hazard Statement	GHS P Statement May cause drowsiness or dizziness. May be fatal if swallowed and enters airways. Causes severe skin burns and eye damage. May cause respiratory irritation. Highly flammable liquid and vapor. Toxic to aquatic life with long lasting effects. Reacts violently with water. May form explosive peroxides. Suspected of causing cancer.
Precautionary Statement	GHS P Statement Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
EINECSNumber	223-893-0
TSCA	TSCA
Recommended Storage	Keep the solution at < 10°C at which it is stable

SDS

RUO – Research Use Only